Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II)

Lair, N.M. and Ng, S.W. and Ali, Hapipah Mohd (2009) Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II). Acta Crystallographica Section E: Structure Reports Online, 65. M1011-U1703. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809029171.

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The central Cd-II atom in the trinuclear title compound, [Cd-3(C14H19N2O3)(2)(CH3COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry. Two of the acetate groups function in a mu(2)-bridging mode, while the other two each chelate to the terminal Cd-II atom and simultaneously bind to the central metal atom in a kappa(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 04 Apr 2013 01:58
Last Modified: 29 Jan 2019 08:36
URI: http://eprints.um.edu.my/id/eprint/5384

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