Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate

Mohd Lair, N. and Ng, S.W. and Ali, Hapipah Mohd (2009) Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate. Acta Crystallographica Section E: Structure Reports Online, 65 (5). m541-m541. DOI .

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The metal atom in the title compound, [Cd(C15H13N2O4)2]·2C2H6OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the -NH- unit, and O-H...O hydrogen bonds link molecules into a supramolecular chain.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 01 Apr 2013 04:37
Last Modified: 21 Aug 2019 09:29

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