Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate

Halim, S.N.A. and Ng, S.W. and Ali, Hapipah Mohd (2010) Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66. M1438-U938. ISSN 1600-5368, DOI

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The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O '- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 01 Apr 2013 04:33
Last Modified: 29 Jan 2019 09:09

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