(2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)

Lee, S.M. and Lo, K.M. and Ali, Hapipah Mohd (2010) (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M793-U719. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810021872.

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In the title compound, [Sn(C4H9)2(C11H12BrNO4)], the Schiff base ligand chelates to the SnIV atom through the two deprotonated hydroxy groups, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at the SnIV atom [C-Sn-C = 129.92 (9)°]. The remaining methylenehydroxy groups engage in O-H...O hydrogen bonding with the O atoms of adjacent molecules, leading to infinite supramolecular chains propagating in [001].

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 01 Apr 2013 02:31
Last Modified: 29 Jan 2019 09:16
URI: http://eprints.um.edu.my/id/eprint/5297

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