Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II)

Salga, M.S. and Ali, Hapipah Mohd and Khaledi, H. (2010) Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II). Acta Crystallographica Section E: Structure Reports Online, 66. M1131-U823. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810032563.

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In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is pentacoordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)ethyl] iminomethyl} phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent molecules are linked together via N-H center dot center dot center dot O and N-H center dot center dot center dot Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C-H center dot center dot center dot Cl interactions into a three-dimensional network.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 27 Mar 2013 07:47
Last Modified: 31 Jan 2019 04:52
URI: http://eprints.um.edu.my/id/eprint/5273

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