{2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)zinc(II)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)zinc(II). Acta Crystallographica Section E: Structure Reports Online, 67. M131-U255. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810053778.

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The asymmetric unit of the title compound, [Zn(NCS)(2)(C13H19N3O)], contains two crystallographically independent molecules. In each molecule, the Zn-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two thiocyanate ligands in a distorted square-pyramidal geometry. The two molecules differ mainly in the deviations from the ideal geometry, with tau values of 0.14 and 0.33. In the crystal, intermolecular C-H center dot center dot center dot S hydrogen bonds are observed. An intramolecular C-H center dot center dot center dot N hydrogen bond occurs in one of the independent molecules.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 26 Mar 2013 01:23
Last Modified: 30 Jan 2019 01:10
URI: http://eprints.um.edu.my/id/eprint/5257

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