Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II)

Hisham, N.A.I. and Gwaram, N.S. and Khaledi, H. and Ali, Hapipah Mohd (2011) Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II). Acta Crystallographica Section E: Structure Reports Online, E67. m55. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810050671.

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In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intramolecular C-H center dot center dot center dot Cl interaction occurs. In the crystal, adjacent molecules are linked together via C-H center dot center dot center dot Cl hydrogen-bonding and long range C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions into a three-dimensional network.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 25 Mar 2013 01:27
Last Modified: 30 Jan 2019 00:57
URI: http://eprints.um.edu.my/id/eprint/5236

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