{2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II). Acta Crystallographica Section E: Structure Reports Online, 67. M58-U661. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810050889.

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In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular pi-pi interaction occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) angstrom.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Single-crystal X-ray study; T = 100 K; mean � (C–C) = 0.002 Å; R factor = 0.023; wR factor = 0.061; data-to-parameter ratio = 18.4
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 21 Mar 2013 01:59
Last Modified: 30 Jan 2019 01:10
URI: http://eprints.um.edu.my/id/eprint/5207

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