Hydrolysis products of dibutyltin dichlorides

Chua, C.K. and Murray, J.D. (1971) Hydrolysis products of dibutyltin dichlorides. Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry. pp. 360-367. ISSN 0022-4944, DOI https://doi.org/10.1039/J19710000360.

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Official URL: https://doi.org/10.1039/J19710000360


The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but instead di-t-butyltin hydroxide chloride is obtained. Under strongly basic conditions di-t-butyltin oxide is formed which has unusual structural properties and can easily be converted into a 'dihydroxide.' Comparative i.r. data derived from analogous systems are presented.

Item Type: Article
Uncontrolled Keywords: Hydrolysis products; dibutyltin dichlorides
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Mr Jasny Razali
Date Deposited: 24 Mar 2021 04:28
Last Modified: 24 Mar 2021 04:28
URI: http://eprints.um.edu.my/id/eprint/24468

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