Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit

Ng, S.W. (2010) Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit. Chinese Journal of Structural Chemistry, 29 (10). pp. 1584-1586.

Full text not available from this repository.

Abstract

Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Dimethyltin dichloride-dibenzyl sulfoxide; Z ` (formula unit per asymmetric crystal unit)
Subjects: Q Science > Q Science (General)
Depositing User: MR Faizal II H
Date Deposited: 28 Dec 2015 08:41
Last Modified: 28 Dec 2015 08:41
URI: http://eprints.um.edu.my/id/eprint/15361

Actions (login required)

View Item View Item