1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole

Jabli, H. and Chahdi, F.O. and Saffon, N. and Essassi, E.M. and Ng, S.W. (2010) 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole. Acta Crystallographica Section E: Structure Reports Online, 66 (1). O232-U3096. ISSN 1600-5368,

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The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with 1,12-diazido-n-dodecane in the presence of catalysts leads to the formation of the title compound, C(38)H(46)N(8)O(2). The seven-membered diazepinyl ring adopts a boat conformation with the azidododecyltriazolylmethyl-bearing C atom as the prow and the fused-ring C atoms as the stern. The octyltriazolylmethyl substituent occupies an axial position.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 28 Dec 2015 01:13
Last Modified: 31 Jan 2019 04:25
URI: http://eprints.um.edu.my/id/eprint/15294

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