(4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate

Cunico, W. and Gomes, C.R.B. and Tiekink, E.R.T. and Vellasco Junior, W.T. and Wardell, J.L. and Wardell, S.M.S.V. (2010) (4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate. Acta Crystallographica Section E: Structure Reports Online, 66 (2). O267-U1594. ISSN 1600-5368,

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The title compound, C(12)H(15)NO(5)S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 angstrom) with the peripheral benzyl and methyl methanesulfonate residues lying to either side of the plane. In the crystal, N-H center dot center dot center dot O hydrogen bonds, involving one of the sulfur-bound oxo groups as acceptor, lead to the formation of supramolecular chains along the b axis. These chains are reinforced by C-H center dot center dot center dot O contacts with the carbonyl O atom accepting three such interactions. The structure was refined as a racemic twin, with the major component being present 89% of the time.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 22 Dec 2015 03:29
Last Modified: 31 Jan 2019 01:48
URI: http://eprints.um.edu.my/id/eprint/15213

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