[mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1)

Meyer, N. and Mohr, F. and Tiekink, E.R.T. (2010) [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1). Acta Crystallographica Section E: Structure Reports Online, 66 (2). M168-U792. ISSN 1600-5368,

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In the title mixed solvate, [Au2Fe(C17H14P)(2)Cl-2]center dot CHCl3 center dot 0.5CH(3)(CH2)(4)CH3, the hexane solvent molecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P, Cl-donor sets, and when viewed down the P center dot center dot center dot P axis the Au atoms are gauche to each other. In the crystal structure, the chloroform solvent molecule is associated with the complex via a C-H center dot center dot center dot Cl contact, and the hexane solvent molecules occupy voids defined by the remaining components of the structure.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 22 Dec 2015 02:40
Last Modified: 31 Jan 2019 04:44
URI: http://eprints.um.edu.my/id/eprint/15205

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