(2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)

Ghafar, N.A.A. and Baba, I. and Yamin, B.M. and Ng, S.W. (2010) (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (2). M208-U1129. ISSN 1600-5368,

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The complete molecule of the title compound, [Zn(C4H8NS2)(2)(C10H8N2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bisects the central C-C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithiocarbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octahedral geometry. The methyl and ethyl groups of the anion are statistically disordered.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 22 Dec 2015 02:46
Last Modified: 31 Jan 2019 04:11
URI: http://eprints.um.edu.my/id/eprint/15201

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