Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate

Broker, G.A. and Tiekink, E.R.T. (2010) Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). O705-U5759. ISSN 1600-5368,

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The asymmetric unit of the title salt, 2C(4)H(12)NO(+)center dot C14H8O4S22-, contains an ethyl(2-hydroxy)aminium cation and half a 2,2'-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydroxy group [the N-C-C-O torsion angle is 66.5 (2)degrees]. A twisted conformation is found for the anion [the C-S-S-C torsion angle is 91.51 (9)degrees and the dihedral angle between the rings is 81.01 (4)degrees]. A supramolecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O-H center dot center dot center dot O- and N+-H center dot center dot center dot O- hydrogen bonding.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: MR Faizal II H
Date Deposited: 02 Dec 2015 03:43
Last Modified: 16 Apr 2019 11:42

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