Bis(3,5-dinitrobenzoato-kappa O-1)tetramethanolcobalt(II)

Sarkar, B. and Roy, A. and Ng, S.W. and Tiekink, E.R.T. (2010) Bis(3,5-dinitrobenzoato-kappa O-1)tetramethanolcobalt(II). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M365-U310. ISSN 1600-5368,

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The Co-II atom (site symmetry 1) in the title complex, [Co(C7H3N2O6)(2)(CH3OH)(4)], exists within an octahedral O-6 donor set defined by two O-monodentate 3,5-dinitrobenzoate anions and four methanol O atoms. An intramolecular O-m-H center dot center dot center dot Oc (m = methanol and c = carbonyl) hydrogen bond leads to the formation of an S(6) ring. In the crystal, centrosymmetrically related molecules associate via further O-m-H center dot center dot center dot Oc hydrogen bonds, leading to linear supramolecular chains propagating along the a-axis direction.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 24 Nov 2015 01:20
Last Modified: 31 Jan 2019 04:53

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