(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)

Reisi, R. and Misran, M. and Lo, K.M. and Ng, S.W. (2010) (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M482-U1350. ISSN 1600-5368,

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The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H center dot center dot center dot O hydrogen bonding with the O atoms of adjacent molecules, generating a chain running along the c axis.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 24 Nov 2015 01:21
Last Modified: 31 Jan 2019 05:17
URI: http://eprints.um.edu.my/id/eprint/14772

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