Aznan, A.M.A. and Fairuz, Z.A. and Abdullah, Z. and Ng, S.W. and Tiekink, E.R.T. (2011) N-(4-Chlorophenyl)-3-nitropyridin-2-amine. Acta Crystallographica Section E: Structure Reports Online, 67 (12). O3176-U1783. ISSN 1600-5368,

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In the title compound, C(11)H(8)ClN(3)O(2), the presence of intramolecular N-H center dot center dot center dot O and C-H center dot center dot center dot N interactions help to establish an almost planar molecule [dihedral angle between the pyridine and benzene rings = 9.89 (8)degrees and r.m.s. deviation for all 17 non-H atoms = 0.120 angstrom]. Supramolecular tapes feature in the crystal packing whereby dimeric aggregates sustained by pairs of C-H center dot center dot center dot O interactions are connected by pi-pi interactions occurring between translationally related pyridine rings and between translationally related benzene rings along the b axis [centroid-centroid distance = length of b axis = 3.8032 (4) angstrom].

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 07 Nov 2015 04:08
Last Modified: 31 Jan 2019 01:14
URI: http://eprints.um.edu.my/id/eprint/14658

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