Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)

Salam, M.A. and Abu Affan, M. and Shamsuddin, M. and Ng, S.W. (2010) Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (5). M570-U939. ISSN 1600-5368,

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The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl-2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: MR Faizal II H
Date Deposited: 23 Oct 2015 02:20
Last Modified: 31 Jan 2019 04:52
URI: http://eprints.um.edu.my/id/eprint/14275

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