{2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride

Shawish, H.B. and Tan, K.W. and Maah, Mohd Jamil and Ng, S.W. (2010) {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1074-U374. ISSN 1600-5368,

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The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 27 Jan 2015 07:56
Last Modified: 30 Jan 2019 09:13
URI: http://eprints.um.edu.my/id/eprint/12418

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