Poly[(mu(3)-4-carboxypyridine-3-carboxylato-kappa N-3:O-3:O-4)(triphenylphosphine-kappa P)silver(I)]

Sadeghi, O. and Amini, M.M. and Ng, S.W. (2010) Poly[(mu(3)-4-carboxypyridine-3-carboxylato-kappa N-3:O-3:O-4)(triphenylphosphine-kappa P)silver(I)]. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1162-U1101. ISSN 1600-5368,

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In the title 1:1 silver(I) 4-carboxypyridine-3-carboxylate adduct with triphenylphosphine, [Ag(C7H4NO4)(C18H15P)](n), the carboxylate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag atom exists in a distorted tetrahedral geometry. The H atom of the carboxylate is midway between two O atoms of the two carboxyl groups, thus forming a strong intramolecular hydrogen bond.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 27 Jan 2015 07:56
Last Modified: 31 Jan 2019 04:50
URI: http://eprints.um.edu.my/id/eprint/12416

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