Muthalib, A.F.A. and Baba, I. and Tahir, M.I.M. and Ng, S.W. and Tiekink, E.R.T. (2010) (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1087-U491. ISSN 1600-5368,

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The Sn(IV) atom in the title organotin dithiocarbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intramolecular C-H center dot center dot center dot Cl and C-H center dot center dot center dot S contacts precludes the Cl and S atoms from forming significant intermolecular contacts. The presence of C-H center dot center dot center dot pi contacts leads to the formation of supramolecular arrays that stack along the b axis.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 27 Jan 2015 07:56
Last Modified: 31 Jan 2019 04:47
URI: http://eprints.um.edu.my/id/eprint/12414

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