Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)]

Li, Yu-Yang and Wei, Zhen-Hong and Ng, S.W. (2010) Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1313-U1326. ISSN 1600-5368,

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The title compound, [AgCd(NCS)(3)(C22H17N3)](n), is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2-'' terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the Ag atom is coordinated by the four S atoms of four thiocyanate ions in a distorted tetrahedral geometry. Of the three thiocyanate ions, one functions in a mu 2-bridging mode and two in a mu 3-bridging mode. The ribbon coordination polymer propagates along the a-axis.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:45
Last Modified: 31 Jan 2019 04:39
URI: http://eprints.um.edu.my/id/eprint/12197

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