[2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridomanganese(II)

Li, Xiao-Ping and Zhao, Jian-She and Ng, S.W. (2010) [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridomanganese(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1298-U1185. ISSN 1600-5368,

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In the molecule of the title compound, [MnCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn-II atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak intermolecular C-H center dot center dot center dot Cl hydrogen bonding occurs in the crystal structure.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:45
Last Modified: 31 Jan 2019 04:38
URI: http://eprints.um.edu.my/id/eprint/12195

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