Gao, S. and Ng, S.W. (2010) Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1279-U1034. ISSN 1600-5368,

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The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)(2)(C4H5N3)(2)-(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octahedron. Intramolecular N-H center dot center dot center dot O hydrogen bonds occur. In the crystal, adjacent adduct molecules are linked by O- H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds into a layer motif parallel to ( 001).

Item Type: Article
Subjects: Q Science > Q Science (General)
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:44
Last Modified: 20 Jan 2015 04:43

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