(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-kappa N-2(1),S]methyl}phenolato-kappa O-1)(triphenylphosphane-kappa P)nickel(II) chloride

Shawish, H.B. and Maah, Mohd Jamil and Ng, S.W. (2010) (6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-kappa N-2(1),S]methyl}phenolato-kappa O-1)(triphenylphosphane-kappa P)nickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1366-U286. ISSN 1600-5368,

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The deprotonated Schiff base ligand in the title salt, [Ni(C9H10N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 14 Jan 2015 02:06
Last Modified: 30 Jan 2019 09:13
URI: http://eprints.um.edu.my/id/eprint/11999

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