Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate

Halim, S.N.A. and Ali, H.M. and Ng, S.W. (2010) Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1438-U938. ISSN 1600-5368,

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The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O `- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 14 Jan 2015 02:00
Last Modified: 29 Jan 2019 09:11

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