Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate

Halim, S.N.A. and Ali, H.M. and Ng, S.W. (2010) Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1439-U950. ISSN 1600-5368,

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In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110].

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 14 Jan 2015 01:59
Last Modified: 29 Jan 2019 09:11

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