Bis[4-(dimethyl-amino)pyridinium] tribromidochloridodimethyl-stannate(IV).

Lo, K.M.; Ng, S.W. (2008) Bis[4-(dimethyl-amino)pyridinium] tribromidochloridodimethyl-stannate(IV). Acta crystallographica. Section E, Structure reports online, 64 (Pt 6). m834. ISSN 1600-5368

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Abstract

The Sn(IV) atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(3)(CH(3))(2)Cl], lies on a center of inversion in a tetra-gonally compressed octa-hedron; two independent Br atoms share the same site as two independent chlorine atoms so that the anion effectively has one Cl and three Br atoms. The occupancies of the Br atoms are 0.721 (1) and 0.779 (1), and those of the Cl atoms are 0.279 (1) and 0.221 (1). The crystal structure involves N-H⋯halogen hydrogen bonds.

Item Type: Article
Creators:
  1. Lo, K.M.
  2. Ng, S.W.
Journal or Publication Title: Acta crystallographica. Section E, Structure reports online
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 22 Apr 2011 09:52
Last Modified: 22 Apr 2011 09:52
URI: http://eprints.um.edu.my/id/eprint/895

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