Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV).

Teo, Y.Y.; Lo, K.M.; Ng, S.W. (2008) Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). Acta crystallographica. Section E, Structure reports online, 64 (Pt 6). m819. ISSN 1600-5368

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Abstract

In the title salt, [Ag(C(26)H(24)P(2))(2)][Sn(C(2)ClF(2)O(2))(2)(C(6)H(5))(2)(C(6)H(4)Cl)], the Ag(I) atom has a tetra-hedral and the Sn(IV) atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chloro-difluoro-methyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30).

Item Type: Article
Creators:
  1. Teo, Y.Y.
  2. Lo, K.M.
  3. Ng, S.W.
Journal or Publication Title: Acta crystallographica. Section E, Structure reports online
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 22 Apr 2011 09:45
Last Modified: 22 Apr 2011 09:45
URI: http://eprints.um.edu.my/id/eprint/891

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