Ng, S.W. (2008) Poly[(μ(3)-nicotinato-κO:O':N)(μ(2)-nicotinato-κO,O':N)iron(II)]. Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 5). m728. ISSN 1600-5368, DOI 21202251.
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Official URL: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC296119...
Abstract
In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O'-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two nicotinate groups result in a polymeric three-dimensional network structure. The Fe atom shows octa-hedral coordination geometry but one of the Fe-O bonds is somewhat long [2.522 (2) Å].
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Mr. Faizal Hamzah |
| Date Deposited: | 21 Apr 2011 03:16 |
| Last Modified: | 31 Jan 2019 02:18 |
| URI: | http://eprints.um.edu.my/id/eprint/858 |
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