Lo, K.M.; Ng, S.W. (2008) Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag). Acta crystallographica. Section E, Structure reports online, 64 (Pt 5). m717. ISSN 1600-5368Full text not available from this repository.
The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro-difluoro-acetate ligand, giving T-shaped geometries and short intra-molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol-ecule, the unique -CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively.
|Journal or Publication Title:||Acta crystallographica. Section E, Structure reports online|
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculty of Science > Dept of Chemistry|
|Depositing User:||Mr. Faizal Hamzah|
|Date Deposited:||21 Apr 2011 10:04|
|Last Modified:||21 Apr 2011 10:32|
Actions (login required)