Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).

Lo, K.M.; Ng, S.W. (2008) Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag). Acta crystallographica. Section E, Structure reports online, 64 (Pt 5). m717. ISSN 1600-5368

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Abstract

The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro-difluoro-acetate ligand, giving T-shaped geometries and short intra-molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol-ecule, the unique -CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively.

Item Type: Article
Journal or Publication Title: Acta crystallographica. Section E, Structure reports online
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 21 Apr 2011 10:04
Last Modified: 21 Apr 2011 10:32
URI: http://eprints.um.edu.my/id/eprint/846

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