Lo, K.M. and Ng, S.W. (2008) Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag). Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 5). m717. ISSN 1600-5368, DOI 21202244.
Full text not available from this repository.Abstract
The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro-difluoro-acetate ligand, giving T-shaped geometries and short intra-molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol-ecule, the unique -CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Mr. Faizal Hamzah |
| Date Deposited: | 21 Apr 2011 02:04 |
| Last Modified: | 31 Jan 2019 02:22 |
| URI: | http://eprints.um.edu.my/id/eprint/846 |
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