(2E)-1-(6-Chloro-2-methyl-4-phenylquinolin-3-yl)-3-phenylprop-2-en-1-one

Tan, Kong Wai and Tiekink, E.R.T. and Viji, A.J. and Sarveswari, S. and Vijayakumar, V. (2010) (2E)-1-(6-Chloro-2-methyl-4-phenylquinolin-3-yl)-3-phenylprop-2-en-1-one. Acta Crystallographica Section E: Structure Reports Online, 66. O1780-U380. ISSN 1600-5368, DOI https://doi.org/10.1107/s160053681002386x.

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Abstract

In the title compound, C(25)H(18)ClNO, the conformation about the C=C double bond is E. Significant twists are evident in the molecule, with the benzene ring forming a dihedral angle of 53.92 (11)degrees with the quinolinyl residue. Further, the chalcone residue is approximately perpendicular to the quinolinyl residue [C(q)-C(q)-C(c)-O(c) torsion angle = -104.5 (3)degrees, where q = quinolinyl and c = chalcone]. In the crystal, the presence of C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions leads to supramolecular layers lying parallel to ((1) over bar 02).

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	Derivatives
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	03 Jul 2013 09:06
Last Modified:	30 Jan 2019 08:41
URI:	http://eprints.um.edu.my/id/eprint/8036

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