Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate

Tan, Kong Wai and Ng, S.W. and Ng, C.H. and Maah, Mohd Jamil (2010) Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (5). ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536810014522.

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Abstract

In the dinuclear title compound, [Zn2(C14H 12N3O2S)2Cl2] ·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:Ochelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a square pyramid surrounding each metal atom. The solvate Dimethylformamide molecules, one of which is disordered over two positions in a 3:1 ratio, are hydrogen bonded to the dinuclear molecule. © 2010.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	Tetra
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	03 Jul 2013 09:30
Last Modified:	31 Jan 2019 05:28
URI:	http://eprints.um.edu.my/id/eprint/8035

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