Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate

Tan, Kong Wai and Ng, S.W. and Tajidi, N.S.A. and Abdullah, N. and Arifin, Z. (2010) Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66. M889-U302. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810025705.

Preview

PDF Tajidi-2010-Diaqua(1,4,8,11-tetr.pdf - Published Version Download (435kB)

Abstract

The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (001).

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	1,4,8,11-tetraazacyclotetradecane (cyclam) ligand; Jahn-Teller-type; Octahedral geometry; Water molecules, Hydrogen bonds
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	05 Jul 2013 03:52
Last Modified:	30 Jan 2019 08:36
URI:	http://eprints.um.edu.my/id/eprint/8030

Actions (login required)

View Item