Tan, Kong Wai and Ng, S.W. and Asiri, A.M. and Khan, S.A. (2010) 4-{[4-(Dimethylamino)benzylidene]amino}-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one. Acta Crystallographica Section E: Structure Reports Online, 66. O1751-U120. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810023536.
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Asiri-2010-4-{_4-(Dimethylamino.pdf - Published Version Download (385kB) |
Official URL: http://journals.iucr.org/e/issues/2010/07/00/kp226...
Abstract
The azomethine double-bond in the title Schiff base, C(20)H(22)N(4)O, has an E-configuration. The aromatic ring of the benzylidene portion (r.m.s. deviation 0.011 angstrom) and the five-membered pyrazolyl ring (r.m.s. deviation 0.033 angstrom) form a dihedral angle of 19.0 (1)degrees. The phenyl substituent is twisted by 55.0 (1)degrees with respect to the five-membered ring.
Item Type: | Article |
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Funders: | UNSPECIFIED |
Additional Information: | Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA |
Uncontrolled Keywords: | Azomethine double-bond; Schiff base; E-configuration; Aromatic ring; Benzylidene portion; Pyrazolyl ring; Dihedral; Phenyl substituent |
Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Science > Department of Chemistry |
Depositing User: | Miss Malisa Diana |
Date Deposited: | 05 Jul 2013 08:41 |
Last Modified: | 30 Jan 2019 08:48 |
URI: | http://eprints.um.edu.my/id/eprint/8019 |
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