Structural and electrochemical investigation of LiNi0.8Co0.2-xMxO2 (M = Al, Al plus Mg, Al plus Mg plus Fe) synthesized by solid-state method

Sethuprakhash, V. and Basirun, Wan Jefrey (2008) Structural and electrochemical investigation of LiNi0.8Co0.2-xMxO2 (M = Al, Al plus Mg, Al plus Mg plus Fe) synthesized by solid-state method. Ionics, 14 (6). pp. 501-507. ISSN 0947-7047, DOI https://doi.org/10.1007/s11581-008-0207-2.

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Abstract

Lithium nickel cobalt oxide materials doped with Al, Mg, and Fe were synthesized by solid-state reaction at 800 degrees C for 18 h to study the effects of adding transition and nontransition metals to the structure. Crystalline compounds were obtained as revealed by powder X-ray diffraction (XRD). Energy dispersive analysis of X-rays (EDAX) was used to determine the elemental ratio of all the samples. Impedance measurements showed that all samples have decreasing conductivities at higher temperatures and gave negative activation energies. The addition of nontransition metals actually decreased the conductivities of the materials.

Item Type: Article
Funders: UNSPECIFIED
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Cathode materials, Lithium nickel oxide, Lithium nickel cobalt oxide, Secondary lithium cells, Li-ion batteries, Linio2, Lini0.7co0.3o2, Substitution, Behavior
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 25 Jul 2013 01:25
Last Modified: 31 Jan 2019 07:21
URI: http://eprints.um.edu.my/id/eprint/7560

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