Conductivity studies of grafted natural rubber and ionic liquid electrolyte systems

Rahmat, M.F. and Alias, Yatimah and Basirun, Wan Jefrey and Aldous, L. and Hardacre, C. (2009) Conductivity studies of grafted natural rubber and ionic liquid electrolyte systems. Malaysian Journal of Science, 28 (2). pp. 209-215. ISSN 1394-3065

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Abstract

Ionic liquids containing the 1 -butyl- 1-methylpyrrolidinium ([C 4mPyrr]+) cation and bis(trifluoromethanesulfonyl)imide ([NTf 2]") anion have been synthesized and incorporated in 49% PMMA grafted natural rubber together with lithium salts to obtain solid polymer electrolytes (SPEs). The resultant SPEs obtained, are freestanding, flexible film and translucent and show conductivity over a wide range of 10 -3-10 -5 S cm -1. Polymer electrolytes containing 80% of (MG49:LiCF 3S0 3) and 20% of [C 4mPyrr] [NTf 2] showed the highest conductivity of 2.11 x 10 -3 S cm -1 at room temperature. The examination of the ion- polymer interactions and ionic conductivity are discussed and investigated by FT-IR and Electrochemical Impedance Spectroscopy (EIS) respectively.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Room temperature ionic liquid; Solid polymer electrolyte; PMMA grafted natural rubber
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 31 Jul 2013 01:30
Last Modified: 31 Jan 2019 08:21
URI: http://eprints.um.edu.my/id/eprint/7557

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