Diffusion coefficient of tin(II) methanesulfonate In Ionic Liquid and Methane Sulfonic ccid (MSA) solvent

Yang, K.K. and Basirun, Wan Jefrey and Koay, H.L. and Ebadi, M. and Mahmoudian, M.R. (2011) Diffusion coefficient of tin(II) methanesulfonate In Ionic Liquid and Methane Sulfonic ccid (MSA) solvent. Metallurgical and Materials Transactions B, 42 (6). pp. 1274-1279. ISSN 1073-5615 , DOI https://doi.org/10.1007/s11663-011-9560-z.

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Official URL: https://doi.org/10.1007/s11663-011-9560-z

Abstract

Voltammetry and chronoamperometry for the electrodeposition of tin from Tin(II) methane sulfonate mixed with ionic liquid and methane sulfonate acid at room temperature was studied. Cyclic voltammetry shows redox waves of Tin(II), which proves that the electrodeposition of tin from Tin(II) methane sulfonate is a diffusion-controlled process. The diffusion coefficient of Tin(II) ions in the solvent mixture showed good agreement from both voltammetry and chronoamperometry results. The diffusion coefficient of Tin(II) in the mixture was much smaller than in aqueous solution, and it depends on the anion of the ionic liquid. © The Minerals, Metals & Materials Society and ASM International 2011.

Item Type: Article
Funders: UNSPECIFIED
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Diffusion-controlled process; Methane sulfonic acid; Methanesulfonates; Redox waves; Room temperature; Solvent mixtures; Chronoamperometry; Cyclic voltammetry; Diffusion; Electrodeposition; Ionic liquids; Methane; Tinning; Tin
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 25 Jul 2013 01:24
Last Modified: 26 Oct 2018 04:14
URI: http://eprints.um.edu.my/id/eprint/7537

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