(4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)(1, 10-phenanthroline-kappa N-2,N ')zinc(II) dimethyl sulfoxide disolvate monohydrate

Tan, Kong Wai and Ng, S.W. and Maah, Mohd Jamil and Ng, C.H. (2009) (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)(1, 10-phenanthroline-kappa N-2,N ')zinc(II) dimethyl sulfoxide disolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 65. M61-U686. ISSN 1600-5368, DOI https://doi.org/10.1107/s160053680804169x.

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Abstract

The Zn-II atom in the title compound, [Zn(C8H7N3O2S)-(C12H8N2)]center dot 2C(2)H(6)OS center dot H2O, is N,N '-chelated by the N-heterocycle and N, O, S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear molecule, the water and the dimethyl sulfoxide (DMSO) molecules into a linear chain motif. One DMSO molecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	10 Jul 2013 00:37
Last Modified:	30 Jan 2019 08:52
URI:	http://eprints.um.edu.my/id/eprint/6961

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