Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetra­kis(μ-2-hydroxy­benzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetra­tin(IV)

Reisi, Reza and Shahirin, Siti Munirah and Misran, Misni and Lo, Kong Mun and Ng, Seik Weng (2008) Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetra­kis(μ-2-hydroxy­benzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetra­tin(IV). Acta Crystallographica Section E: Structure Reports Online, 64 (8). m1103. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536808023787.

[img]
Preview
 PDF
Octa-n-butyl-1kappaC,2kappaC,3kappaC,4kappaC-tetra-kis(mu-2-hydroxy-benzoato)-12_kappaOO;23kappaOO';34kappaOO;14kappaOO'-di-mu(3)-oxido-123kappaOOO;13_4kappaOOO-tetra-tin.pdf - Published Version
Download (499kB)
Official URL: https://doi.org/10.1107/S1600536808023787

Abstract

In the centrosymmetric tetra­nuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) inter­action [Sn⋯O = 2.862 (1) Å]. The other Sn atom has a bent R 2Sn skeleton [C—Sn—C = 144.0 (1)°], but the geometry is best regarded as being a trans-C2SnO4 octa­hedron as the Sn–O(single bond) inter­action is shorter [Sn—O = 2.674 (1) Å].

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Tetra
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: miss munirah saadom
Date Deposited: 08 Jul 2013 06:50
Last Modified: 11 Dec 2020 06:39
URI: http://eprints.um.edu.my/id/eprint/6850

Actions (login required)

View Item View Item
UM Research Repository is powered by EPrints 3 which is developed by the School of Electronics and Computer Science at the University of Southampton. More information and software credits.