2-N-Anilinopurine, 2- N-Piperidinopurine, 2-N-Phenylalaninopurine and 2-N- Prolinopurine: fluorescence characteristics

Abdullah, Z. and Shariffuddin, M.A.M. and Bakar, N.K.A. and Idris, A.M. (2007) 2-N-Anilinopurine, 2- N-Piperidinopurine, 2-N-Phenylalaninopurine and 2-N- Prolinopurine: fluorescence characteristics. Malaysian Journal of Chemistry, 9 (1). pp. 22-28.

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Abstract

2-N-Anilinopurine, 2-N-Piperidinopurine, 2-N-Phenylalaninopurine and 2-NProlinopurine were obtained when 2-fluoropurine was reacted with aniline, piperidine, phenylalanine and proline respectively. The structures of all the compounds were confirmed by infrared, 1H NMR and mass spectrometries. The fluorescence characteristics of these 2-substituted purines were studied in 75 ethanol. 2-N-Anilinopurine showed the highest fluorescence intensity followed by 2-N-Piperidinopurine, 2-N-Phenylalaninopurine and 2-N-Prolinopurine showed the least intensity. 2-N-Anilinopurine, 2-N-piperidinopurine and 2-N-phenylalaninopurine were excited at 340 nm and the fluorescence peaks were observed at 473, 490 and 490 nm respectively, while 2-prolinopurine was excited at 385 nm, and fluoresced at 470 nm.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: 2-N-Anilinopurine, 2-N-Piperidinopurine, 2-N-Phenylalaninopurine and 2-NProlinopurine
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: miss munirah saadom
Date Deposited: 02 Jul 2013 01:34
Last Modified: 02 Jul 2013 01:34
URI: http://eprints.um.edu.my/id/eprint/6236

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