S-[4-(Trimethylammonio)phenyl] thiosulfate, an aromatic organic thiosulfate

Chen, J.X. and Lang, J.P. and Ng, S.W. and Zain, Sharifuddin Md and Zhang, Y. and Xu, Q.F. (2004) S-[4-(Trimethylammonio)phenyl] thiosulfate, an aromatic organic thiosulfate. Acta Crystallographica Section C: Crystal Structure Communications, 60 (8). o572-o574. ISSN 01082701, DOI https://doi.org/10.1107/S010827010401443X.

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Abstract

The title compound, C9H13NO3S2, exists as a zwitterion with crystallographic mirror symmetry. The central S atom of the S2O3 group adopts a slightly distorted tetrahedral coordination geometry. The S-S bond length is 2.1137 (7) Å, while the S-O bond lengths are in the range 1.4417 (12)-1.457 (2) Å. The zwitterions in the crystal adopt a head-to-tail arrangement, which leads to the formation of a three-dimensional network through C-H ⋯ O hydrogen bonds.

Item Type: Article
Funders: UNSPECIFIED
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Bond lengths, Head-to-tail arrangement, Tetrahedral coordination geometry, Zwitterionic compounds, Ammonium compounds, Crystal symmetry, Crystallography, X-Ray Ethers, Hydrogen bonds, Methanol, Positive ions, Thermal effects, Aromatic compounds
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 19 Apr 2013 01:01
Last Modified: 25 Oct 2019 08:56
URI: http://eprints.um.edu.my/id/eprint/5843

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