{4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate

Ali, Hapipah Mohd and Yamin, B.M. and Basirun, Wan Jefrey and Khamis, N.A. (2004) {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate. Acta Crystallographica Section E: Structure Reports Online, 60 (9). m1351-m1352. ISSN 1600-5368

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Abstract

The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands. © 2004 International Union of Crystallography Prinled in Great Britain - all rights reserved.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Benzene, Carrier concentration, Chemical bonds, Complexation, Coordination reactions, Crystal structure, Crystallization, Ethanol, Filtration, Hydrazine, Molecular structure, Organometallics, 2-hydroxyacetophenone, Benzhydrazide moiety, Octahedral coordination, Pyridine ligands, Nickel compounds
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 04 Jan 2013 16:51
Last Modified: 31 Jan 2019 06:42
URI: http://eprints.um.edu.my/id/eprint/5635

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