Ali, Hapipah Mohd and Yamin, B.M. and Basirun, Wan Jefrey and Khamis, N.A. (2004) {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate. Acta Crystallographica Section E: Structure Reports Online, 60 (9). m1351-m1352. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536804020756.
Full text not available from this repository.Abstract
The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands. © 2004 International Union of Crystallography Prinled in Great Britain - all rights reserved.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Additional Information: | Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA |
| Uncontrolled Keywords: | Benzene, Carrier concentration, Chemical bonds, Complexation, Coordination reactions, Crystal structure, Crystallization, Ethanol, Filtration, Hydrazine, Molecular structure, Organometallics, 2-hydroxyacetophenone, Benzhydrazide moiety, Octahedral coordination, Pyridine ligands, Nickel compounds |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Miss Malisa Diana |
| Date Deposited: | 04 Jan 2013 16:51 |
| Last Modified: | 31 Jan 2019 06:42 |
| URI: | http://eprints.um.edu.my/id/eprint/5635 |
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