{4-Chloro-2′-[(3-methoxy-2-oxidophenyl)-methylidene]benzohydrazido} (pyridine)-copper(II)

Ali, Hapipah Mohd and Yamin, B.M. and Basirun, Wan Jefrey and Khamis, N.A. (2004) {4-Chloro-2′-[(3-methoxy-2-oxidophenyl)-methylidene]benzohydrazido} (pyridine)-copper(II). Acta Crystallographica Section E: Structure Reports Online, 60 (7). m982-m983. ISSN 1600-5368

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Abstract

In the title compound, [Cu(C15H11ClN 2O3)(C5H5N)], the hydrazide ligand chelates to the central Cu atom in an O,N,O′-tridentate manner and the pyridine molecule coordinates through the N atom, forming a distorted square-planar geometry. The compound has a trans configuration with cis angles about the Cu atom between 81.1 (2) and 95.7 (2)°. The molecule is discrete, with no significant intermolecular interactions. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Aromatic compounds, Chelation, Condensation, Copper compounds, Crystal structure, Crystallization, Geometry, Molecular structure, Probability, Single crystals, Synthesis (chemical), X rays, Hydrazide ligand chelates, Schiff base metal complexes, Square-plane geometry, Tetrahedral geometry, Organometallics
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 04 Jan 2013 16:52
Last Modified: 31 Jan 2019 06:41
URI: http://eprints.um.edu.my/id/eprint/5633

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