2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide

Ali, Hapipah Mohd and Yamin, B.M. and Sahali Mardi, A. and Khamis, N.A. and Sukeri Yusof, M. (2004) 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide. Acta Crystallographica Section E: Structure Reports Online, 60 (9). o1656-o1658. ISSN 1600-5368

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Abstract

The title compound, C15H11Cl2N 3O2S, has a similar structure and similar structural dimensions to the unsubstituted N-(N-benzoylhydrazinocarbothioyl)benzamide. However, the presence of Cl atoms at the para and ortho positions in the benzamide and benzoyl groups, respectively, caused the dihedral angle between these groups to increase from 16.42 (14)° in the unsubstituted compound to 74.96 (8)°. The molecule is stabilized by intermolecular C-H⋯O and N-H⋯S interactions, forming polymeric chains parallel to the c axis. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Acetone, Complexation, Crystal structure, Crystallization, Hydrazine, Hydrogen bonds, Isomers, Molecular dynamics, Molecular structure, Precipitation (chemical), Substitution reactions, X ray analysis, Atom numbers, Displacement ellipsoids, Intermolecular hydrogen bonds, Thiourea, Benzene
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 05 Jan 2013 11:48
Last Modified: 31 Jan 2019 06:43
URI: http://eprints.um.edu.my/id/eprint/5622

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