Yusnita, J. and Ali, Hapipah Mohd and Robinson, W.T. and Abdulla, M.A. and Puvaneswary, S. (2009) Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex. Journal of Chemical Crystallography, 39 (9). pp. 615-618. ISSN 1074-1542, DOI https://doi.org/10.1007/s10870-009-9540-1.
Full text not available from this repository.Abstract
2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) angstrom, b = 16.328(2) angstrom, c = 8.2670(11) angstrom, beta = 91.869(9)degrees, while the zinc( II) complex crystallizes in the orthorhombic crystal system, space group Pbcn, with cell parameters a = 14.5927(3) angstrom, b = 9.6502(2) angstrom, c = 20.5610(5) angstrom. The metal center is seven-coordinate, with an approximate pentagonal bipyramidal configuration of the chelating ligand and two apically coordinated DMSO molecules.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Additional Information: | Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA |
| Uncontrolled Keywords: | 2,6-Diacetylpyridinebis(benzenesulfonylhydrazide); Zinc(II) complex; Pentagonal bipyramidal |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Miss Malisa Diana |
| Date Deposited: | 05 Apr 2013 02:08 |
| Last Modified: | 29 Jan 2019 08:35 |
| URI: | http://eprints.um.edu.my/id/eprint/5395 |
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