Bis 4-hydroxy-N '-(4-methoxy-2-oxido-benzylidene-kappa O-2)benzohydrazidato-kappa O-2,N ' cadmium(II) dimethyl sulfoxide disolvate

Lair, N.M. and Ng, Seik Weng and Ali, Hapipah Mohd (2009) Bis 4-hydroxy-N '-(4-methoxy-2-oxido-benzylidene-kappa O-2)benzohydrazidato-kappa O-2,N ' cadmium(II) dimethyl sulfoxide disolvate. Acta Crystallographica Section E: Structure Reports Online, 65. M541-U720. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809013774.

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Abstract

The metal atom in the title compound, [Cd(C15H13N2O4)(2)]center dot-2C(2)H(6)OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the -NH- unit, and O-H center dot center dot center dot O hydrogen bonds link molecules into a supramolecular chain.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	04 Apr 2013 01:51
Last Modified:	29 Jan 2019 08:53
URI:	http://eprints.um.edu.my/id/eprint/5379

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